Route:

(Forest Ruins) - Get Charge Shot from the cowboy in the Saloon, then do the dungeon as normal (Ninja Cave) - Get Miracle 5 bounty, machine gun and shotgun, do the dungeon as normal. (Red Canyon) - Get revolver in the dungeon (2nd room fall down hole [x2] up [x3] down-left, left [x2] up) then to get back (backtrack to large room, take the southeast exit and follow path to snake room) get coin #1 (in between the two areas of the dungeon, go up the ladder and drop down the ledges to the cave entrance) however, you'll have to go through the entire dungeon again :( (Ghost Town!!!) Get Crazy shot (go to the right of the desert, down the ladder, and up to the screen transition to a house [7-8 hearts required]) , Bounty, Crucifix, to Ghost Town, Iron Fist (3rd house in front row, left, up, right [x2]) then backtrack to normal dungeon route (I'm the only one I'm sure that needs to actually learn Ghost Town) (Abandoned Mines) - literally just do Ghost Town skip, then take the first right you can in the dungeon for coin #2 (Wood Tower) - Deathwarp out of Abandoned Mines, swimming gear, shroyuken, to wood tower, power hand (in dungeon: up-left, up [x2] , right [x2], down) do the dungeon normally afterwards (Stone Tower) No carrot!! by waterfall, go up the ladder and jump off the two ledges, but not onto thee ground and follow path to coin #3, go to town and shroyuken up waterfall (in town) for coin #4 then follow path normally (carrot) but, once you get to the metal shield area, go left and follow that path to above Ninja Cave for the final coin #5 then do Stone Tower... except go (at start of dungeon) take the Northwest stairs, left, down-right, right, up (choose the green suit) do the dungeon normally (Suspicions Mountain) - exactly the same

i dont think anyone that runs this game even knows what 100% fully entails, especially regarding this deluxe combo thing... perhaps contact ben directly via twitch or twitter? sorry i cant be of more help :<

that said im not opppsed to a 100% category as long as all the details are fully fleshed out